葡萄糖酸钠与锌盐对Z30铸铁的缓释协同研究

    采用经典失重法研究了葡萄糖酸钠与硫酸锌复配在3.5％的NaCl、pH值为6.5的去离子水体系中对Z30铸铁的缓蚀效应.结果表明,当葡萄糖酸锌的配比浓度为0.5×10^-3 mol/L和0.75×10^-3 mol/L时,缓蚀率高达92.3%与95.4%,同时借助扫描电镜、动电位实验探讨了其缓蚀机理.      

Cl-浓度对CrCoMo不锈钢耐蚀性能的影响

循环极化研究了CrCoMo不锈钢在去离子水和不同浓度NaCl溶液中的腐蚀行为，探讨了Cl-浓度对其耐蚀性能的影响。结果表明，在NaCl溶液中，CrCoMo不锈钢的耐蚀性能变差，且随着Cl-浓度增加，耐蚀性能降低；腐蚀形貌呈现孔蚀特征。第二相沿晶界析出及夹杂物的存在，使CrCoMo不锈钢表面难以形成完整钝化膜。      

工业纯Ti高线盘条的开发

Ti及Ti合金线材应用广泛，但在热加工过程中容易产生多种缺陷，工业连续化生产困难。以工业纯Ti自身特性、热加工图、碳钢盘条生产经验等为重要依据，设计了工业纯Ti盘条孔型系统，制定了加热、轧制、冷却等工艺参数，并在某高线产线上进行了试制。结果表明，纯Ti盘条组织性能及硬度均满足标准的要求，高速线材轧钢设备生产工业纯Ti高线盘条是可行的。     

二次喷丸42CrMo钢表面完整性的数值模拟研究

目的探究二次喷丸工艺参数对42CrMo钢零件表面完整性的影响规律。方法建立三维随机喷丸有限元模型,并通过实验验证有限元模型预测残余应力的准确性。将一次喷丸后零件的表面形貌和应力应变结果作为初始状态导入到二次喷丸模型中,构建出二次喷丸预测模型。分析二次喷丸参数对42CrMo钢零件表面残余应力场、表面粗糙度以及等效塑性形变场的影响情况。结果二次喷丸后,42CrMo钢零件近表层(0～100μm)的残余压应力值均比初始状态有所增加。增加二次喷丸覆盖率对表面残余应力的提升作用最为明显,最大可比初始状态提高63.3%,而增加二次喷丸直径对残余应力的改善效果最不明显。过度增加二次喷丸速度会导致表面粗糙度明显增加,提高二次喷丸覆盖率可显著降低表面粗糙度,覆盖率为300%时,粗糙度比初始状态减小了14.4%。表层PEEQ值随着二次喷丸速度、弹丸直径和覆盖率的增加而增加,但当二次喷丸速度、弹丸直径和覆盖率增加到一定程度后,表层PEEQ值会趋于饱和。结论二次喷丸预测模型揭示了二次喷丸参数与42CrMo钢零件表面完整性之间的影响规律,为二次喷丸的工业应用提供了一定的参考意义。     

Hydrogen effects on the passive film formation and pitting susceptibility of nitrogen containing type 316L stainless steels

The effects of hydrogen on the passivity and pitting susceptibility of type 316L stainless steels have been investigated with alloys containing different nitrogen contents (0.015, 0.198 and 0.556 wt.% N). The study revealed that electrochemically pre-charged hydrogen significantly reduced the pitting resistance of alloys conatining 0.015 and 0.198 wt.% nitrogen contents. In alloy with highest nitrogen content (0.556 wt.% N), an increase in the passive film current density with hydrogen was observed without affecting breakdown potential. Auger electron spectroscopy (AES) analysis of the passive film indicated the presence of nitrogen in the passive film. On other hand, for hydrogen charged samples, nitrogen was found to be significantly less in the passive film. In Electrochemical impedance spectroscopy (EIS) measurement, the decrease in semi-circle radius of Nyquist plot, and the polarization resistance, R_P associated with the resistance of the passive film was observed with hydrogen, indicating that hydrogen decreased the stability of the passive film. The present investigation indicated that precharged hydrogen deteriorated the passive film stability and pitting corrosion resistance in these alloys, and the increase in nitrogen content of the alloy offsets the deleterious effect of precharged hydrogen.     

基于动态相变的细晶双相低碳钢组织控制

利用Gleeble1500热模拟单向压缩实验机，通过观察不同原奥氏体晶粒的过冷奥氏体在动态相变过程中的组织演变，分析了动态相变过程中马氏体岛形貌以及分布的演变特征，并考察了原奥氏体晶粒大小、形变温度和形变速率等参数对组织转变动力学的影响，探讨了基于动态相变的细晶双相低碳钢的组织控制规律、结果表明，通过调整原始奥氏体晶粒尺寸并控制过冷奥氏体动态相变进程，可以获得在均匀细小的铁素体（2～3μm）基体上弥散分布着不同体积分数、颗粒状细小马氏体岛的双相钢。     

一种咪唑啉缓蚀剂在碳钢表面成膜的电化学研究

利用动电位扫描法研究了咪唑啉缓蚀剂MCI在碳钢表 面成膜的耐蚀性能；通过电化学交流阻抗技术.测量了碳钢表面成膜的EIS谱，并提出其特征等效电路.探讨了缓蚀剂在碳钢表面的缓蚀机理.实验结果表明，在高温高压下碳钢表面经咪唑啉缓蚀剂MCI处理成膜后具有很好的耐蚀性能.     

激光熔化沉积γ／Mo2Ni3Si金属硅化物合金的腐蚀行为

采用极化曲线，塔菲尔图（Tafel Plot），交流阻抗（EIS）及浸泡腐蚀技术，研究了激光熔化沉积γ／Mo2Ni3Si合金在不同酸，碱，盐介质中的腐蚀行为。结果表明，该合金在1mol／L NaOH溶液中，由于形成了稳定的钝化膜，耐蚀性优异；在1mol／LH2SO4溶液中，合金只能形成不稳定的钝化膜；而在含Cl^-的中性或酸性介质中，合金没有钝化趋势，且由浸泡腐蚀试验表明，在1mol／LHCl溶液中，由于Cl^-导致相界腐蚀，合金耐蚀性较差。     

Effect of α-Al/Al3Ni microstructure on the corrosion behaviour of Al-5.4 wt% Ni alloy fabricated by equal-channel angular pressing

The effect of microstructure on corrosion behaviour of an Al-5.4 wt% Ni alloy fabricated by equal-channel angular pressing (ECAP) was investigated by means of potentiodynamic polarization test. The Al-5.4 wt% Ni alloy samples were severely deformed by ECAP with two strain introduction methods of route A and route B_C and the ECAP process was repetitively carried out up to 6 passes (strain 6). The anodic polarization measurements indicated that pitting potential of the ECAPed Al-Ni alloy samples in chloride containing neutral buffer solution increased with ECAP passes. The pitting corrosion resistance of Al-Ni alloy after ECAP by route B_C was better than that by route A. It is attributable to that the size of α-Al crystal region was reduced with ECAP passes and route B_C was able to obtain more homogeneous α-Al/Al₃Ni structure than route A. On the other hand, pitting corrosion resistance of pure Al samples showed an obvious declining with increasing ECAP passes. It was indicated that more homogeneous and finer α-Al/Al₃Ni structure obtained by ECAP played a vital role on improving the corrosion resistance of Al-5.4 wt% Ni alloy.     

Effect of alloying elements on the electrochemical polarization behavior and passive film of Fe-Mn base alloys in various aqueous solutions

The corrosion properties of austenitic Fe-Mn, Fe-Mn-Al, Fe-Mn-Cr and Fe-Mn-Al-Cr alloys with compositions of 23-30 wt% Mn, 2.8-8.2 wt% Al and 4.9-6.9 wt% Cr in various aqueous solutions of pH −0.8 to 15.3 and the passivating mechanism induced by the presence of Al, Cr, or Al and Cr have been studied using electrochemical measurements and Auger electron spectroscopic/X-ray photoelectron spectroscopic analysis. Binary Fe-Mn alloys can be passivated only in 10-50% NaOH solutions, and alloying of binary Fe-Mn alloy with Al or Cr or combination of Al and Cr seems not so obviously beneficial to corrosion resistance in HNO₃ or Na₂SO₄ solutions. All of the experimental Fe-Mn based alloys and steels for comparison cannot passivate in either 10% HCl or 3.5% NaCl solution. The Fe-Mn based alloys containing Al or Cr or Al and Cr can passivate in 10-50% HNO₃ or 1 mol l⁻¹ Na₂SO₄ solutions and rainwater. In general, Fe-Mn based alloys can passivate in oxidizing acid, neutral and basic solution, but cannot passivate in reducing acid or solution containing active Cl⁻ ions. In the passive film formed on the surface of Fe-Mn base alloys in various aqueous solutions, bound water and hydroxides are present at the surface of the film, while mixed oxides of Al, Cr, Mn and Fe are located in the inner part. The resistance to corrosion is imparted by a barrier film of bound water, hydroxides and oxides of Al, Cr or Fe, while the Mn oxides in passive film reduce the corrosion resistance.